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| 1er tour | | 1/4 de finale | | Finale |
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| Łukasz Kubot
Oliver Marach | (1) | 6 | 5 | 11 | | |
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| Albert Ramos
Leonardo Tavares | (Alt) | 3 | 7 | 9 | |
| Łukasz Kubot
Oliver Marach | (1) | | |
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| | | Nicolás Massú
João Souza | (WC) | forfait | |
| Nicolás Massú
João Souza | (WC) | 7 | 7 | |
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| Fabio Fognini
Filippo Volandri | | 63 | 67 | |
| | Łukasz Kubot
Oliver Marach | (1) | 7 | 7 | | |
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| Juan Ignacio Chela
Santiago González | (4) | 65 | 66 | | |
| Juan Ignacio Chela
Santiago González | (4) | 6 | 6 | | | |
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| Jorge Aguilar
Paul Capdeville | (WC) | 3 | 4 | | |
| Juan Ignacio Chela
Santiago González | (4) | 7 | 6 | |
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| | | David Marrero
Rubén Ramírez Hidalgo | | 63 | 2 | |
| David Marrero
Rubén Ramírez Hidalgo | | 6 | 4 | 10 |
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| Franco Ferreiro
Ricardo Mello | | 3 | 6 | 6 |
| | Łukasz Kubot
Oliver Marach | (1) | 3 | 63 | |
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| Marcelo Melo
Bruno Soares | (3) | 6 | 7 | |
| Thomaz Bellucci
Leonardo Mayer | | 6 | 6 | | | |
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| Brian Battistone
Andreas Siljeström | | 3 | 4 | | |
| Thomaz Bellucci
Leonardo Mayer | | forfait | |
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| | | Marcelo Melo
Bruno Soares | (3) | | |
| Carlos Berlocq
Rui Machado | | 1 | 4 | |
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| Marcelo Melo
Bruno Soares | (3) | 6 | 6 | |
| | Marcelo Melo
Bruno Soares | (3) | 6 | 7 | |
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| Eduardo Schwank
Horacio Zeballos | (2) | 4 | 5 | |
| Santiago Giraldo
Daniel Muñoz de la Nava | | 3 | 63 | | | |
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| František Čermák
Leoš Friedl | | 6 | 7 | | |
| František Čermák
Leoš Friedl | | 3 | 3 | |
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| | | Eduardo Schwank
Horacio Zeballos | (2) | 6 | 6 | |
| Pablo Andújar
Potito Starace | | 3 | 4 | |
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| Eduardo Schwank
Horacio Zeballos | (2) | 6 | 6 | |
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